Frida SSL intercept
Overview
The output from these Frida scripts should be entered into Wirehark's '(Pre)-Master-Secret log filename' field under 'TLS' in 'Protocol Preferences'. The files should contain one set of keys per line. The window is shown below.

SSLv3 and TLSv1.0
In order to
function buf2hex(buffer) { // buffer is an ArrayBuffer
return [...new Uint8Array(buffer)]
.map(x => x.toString(16).padStart(2, '0'))
.join('');
}
Interceptor.attach(Module.findExportByName('libssl.so.1.0.0', 'SSL_read'), {
onEnter(args) {
const ssl = ptr(args[0])
const s3 = ssl.add(128).readPointer()
const client_random = s3.add(196).readByteArray(32)
const session = ssl.add(304).readPointer()
const master_key = session.add(20).readByteArray(48)
console.log(`CLIENT_RANDOM ${buf2hex(client_random)} ${buf2hex(master_key)}`)
}
})